(Z)-3-Ferrocenyl-2-phenylacrylonitrile
نویسندگان
چکیده
In the structure of the title compound, [Fe(C(5)H(5))(C(14)H(10)N)], the unsubstituted cyclo-penta-diene (Cp) ring is disordered over two positions, with site-occupancy factors 0.76 (2) and 0.24 (2). The dihedral angles between the substituted Cp ring and the major and the minor components of the disordered ring are 0.9 (5) and 6(2)°, repectively. The plane of the acrylonitrile unit makes dihedral angles of 6.1 (18) and 6.5 (4)° with the substituted Cp ring and the phenyl ring planes, respectively.
منابع مشابه
Zeitschrift für Naturforschung / B / 50 (1995)
According to a single crystal X-ray structure determination all three ferrocenyl substituents of triferrocenylborane (1) adopt the same orientation with respect to the BC3-plane [P 2Jc\ monoclinic; Z = 4; a = 1353.5(3), b = 1695.6(3), c = 1056.4(2) pm, ß = 109.27(3)°]. The simu lated X-ray powder pattern of the single crystal is identical with the powder diagram of a macroscopic sample, indica...
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